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61.
铋(Ⅲ)-溴邻苯三酚红配合物吸附波及其应用*刘家欣段友构黄诚朱苗力(吉首大学化学系湖南吉首416000)匡向阳(永州市水文站湖南永州425000)关键词铋溴邻苯三酚红配合物吸附波中图分类号O657.14近年来,在某些有机试剂存在下用极谱法测定铋已有一... 相似文献
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63.
The 4f-5d transition rates for rare-earth ions in crystals can be calculated with an effective transition operator acting between model 4f(N) and 4f(N-1)5d states calculated with effective Hamiltonian, such as semiempirical crystal Hamiltonian. The difference of the effective transition operator from the original transition operator is the corrections due to mixing in transition initial and final states of excited configurations from both the center ion and the ligand ions. These corrections are calculated using many-body perturbation theory. For free ions, there are important one-body and two-body corrections. The one-body correction is proportional to the original electric dipole operator with magnitude of approximately 40% of the uncorrected electric dipole moment. Its effect is equivalent to scaling down the radial integral (5d/r/4f) to about 60% of the uncorrected HF value. The two-body correction has magnitude of approximately 25% relative to the uncorrected electric dipole moment. For ions in crystals, there is an additional one-body correction due to ligand polarization, whose magnitude is shown to be about 10% of the uncorrected electric dipole moment. 相似文献
64.
trans-RhCl(CO)(TPPTS)2 (TPPTS=tris(m-sulfonatophenyl)phosphine) has been intercalated into Zn-Al layered double hydroxides (LDHs) by the method of ion exchange. The structure, composition and thermal stability of the composite material have been characterized by powder X-ray diffraction, Fourier transform infrared and 31P solid-state magic-angle spinning nuclear magnetic resonance spectroscopy, elemental analysis, thermogravimetry, and differential thermal analysis. The geometry of trans-RhCl(CO)(TPPTS)2 was fully optimized using the PM3 semiempirical molecular orbital method, and a schematic model for the intercalated species has been proposed. The thermal stability of trans-RhCl(CO)(TPPTS)2 is significantly enhanced by intercalation, which suggests that such materials may have prospective application as the basis of a supported catalyst system for the hydroformylation of higher olefins. 相似文献
65.
Study on the Phase Diagram of CsCl-CeCl3-HCl(11%)-H2O System and the Properties of the Compounds 总被引:2,自引:0,他引:2
The equilibrium solubility of CsCl-CeCl3-HCl(11%)-H2O qua-ternary system at 25℃ has been determined by the physicchemical analysis method ,and the phase diagram was plotted, Two new double salts 3CsCl.CeCl3.3H2O and CsCl.CeCl3.4H2O obtained from the complicated system were identified and characterized by XRD,TG-DTA ,DSC,UV and fluorescence spectroscopy, Studies on the fluorescence excitation and emission show that 3CsCl.CeCl3.3H2O and CsCl.CeCl3.4H2O have upconversion luminescence of infrared-visible range,and the upconversion emission intensity increases with the increase of ratio of CeCl3 in CsCl. 相似文献
66.
膜渗透与离子色谱联用技术测定蔬菜中亚硝酸盐和硝酸盐 总被引:1,自引:0,他引:1
建立了膜渗析与离子色谱联用技术分析蔬菜等复杂基体中亚硝酸盐和硝酸盐的方法。蔬菜样品经沸水浴后,试样液通过膜渗析除去水溶性大分子杂质和颗粒,直接进入离子色谱分析。渗析池采用0.20μm的醋酸纤维为渗析膜,以水为接收液,分析柱为Metrosep A Supp4-250阴离子交换柱,以1.8mmol/L Na2CO3 1.7mmol/L NaHCO3为流动相,采用化学抑制电导检测。以20g称样计量,方法中NO2-、NO3-的检出限分别为0.075mg/kg和0.105mg/kg;实际样品的加标回收率分别为80.6%~98.7%和90.5%~114%;相对标准偏差(RSD)≤10%。本方法前处理简单,重现性好,准确度高。 相似文献
67.
氢化物发生原子荧光光谱法测定铅基合金中砷 总被引:3,自引:0,他引:3
建立了以HG-AFS测定铅基合金样品中砷的简单方法,研究了共存元素可能引起的干扰并成功地加以解决,优化了氢化物发生条件及仪器的工作参数。KBH4最优浓度为1.0%(m/V),样品溶液和载流中HCl的最优浓度分别为10%(V/V)和5%(V/V)。实验表明,当硫脲存在时,Cu不干扰As的测定;Sb、Sn和Bi引起的干扰可以通过0.5%(m/V)KMnO4溶液在线吸收相应的氢化物加以消除。通过测定铅基合金标准样品以检验方法的准确性,由标准加入法得到的结果与标准值吻合。本方法的检出限为0.17μg/L,对40μg/LAs标准溶液连续测定11次的相对标准偏差为1.45%。 相似文献
68.
Guangyin Zhou Wen Jiang Yan Zhao Guang-En Ma Shengguang Li Wenjuan Xin Baolu Zhao 《Research on Chemical Intermediates》2002,28(4):277-289
Adriamycin (ADR) is a powerful and widely used antitumor drug, but its dose dependent cardiotoxicity limits its application. This side effect is believed to be caused by the adriamycin semiquinone free radical (ASFR). The primary focus of this work is to test effects of sodium tanshinone IIA sulfonate (STS) on ASFR and adriamycin–induced lipid peroxidation. It was found that ADR, whether in the system of heart homogenate, heart mitochondria or heart submitochondria, with NADH as the substrate or in xanthine/xanthine oxidase under anaerobic conditions, all produced ASFR rapidly. STS was shown to effectively scavenge ASFR in all these systems and postpone the appearance of ASFR. The delayed time was proportional to the amount of STS. Under aerobic conditions, ASFR could be oxidized to generate oxygen free radicals. STS could not scavenge these oxygen free radicals, but it could effectively scavenge lipid free radicals generated from membrane lipid peroxidation of heart mitochondria. STS could significantly reduce mitochondrial swelling and lipid peroxidation induced by ADR. Animal experiments show that treatment of STS could inhibit endogenous lipid peroxidation caused by ADR. Here, a protective mechanism of STS is suggested that STS can rapidly and univalently oxidize ASFR, causing the cycle of adriamycin between its quinone form and semiquinone form and inhibiting the accumulation of ASFR. Under aerobic condition, STS can protect heart mitochondria by scavenging lipid free radicals generated from adriamycin-induced mitochondrial lipid peroxidation. This investigation shows that STS may be a physiological drug to antagonize the cardiotoxicity of ADR. 相似文献
69.
建立了用阴离子交换分离柱、化学抑制模式、电导检测测定系列离子液体中BF-4阴离子及其他杂阴离子(F-、Cl-、Br-)含量的方法,并用于在线监控离子液体合成工艺中阴离子杂质含量.确定淋洗液组成为1.6 mmol/L Na2CO3+3.9 mmol/L NaHCO3,流速为0.6 mL/min.本方法对所测阴离子检出限分别为50 μg/L(F-、Br-)和80 μg/L(BF-4);线性范围在3个数量级以上;r>0.999;回收率在98%~102%之间.方法用于对离子液体小试工艺样品分析及过程监控时,结果满意,样品的RSD小于2.6%(n=6). 相似文献
70.
使用BeckmannDU-8B紫外可见分光光度计研究了以氯合四-间三甲苯基卟啉铁(Ⅲ)(FeTMPCl)为催化剂,间氯过氧化苯甲酸(mCPBA)为氧化剂,咪唑(I_m)、2-甲基咪唑(MeI_m)、2-乙基-4-甲基咪唑(EMI_m)为轴向配体,催化β-胡萝卜素(β-cte)氧化分解为维生素A的动力学规律,提出了反应机理,研究了温度、催化剂浓度、氧化剂浓度及轴向配体对反应速率的影响,应用Gauss-Newton-Marquardt方法求得各基元反应的有关动力学参数. 相似文献